5.已知向量a→\overrightarrow{a}a,b→\overrightarrow{b}b满足∣a→∣=3\vert {\overrightarrow{a}}\vert =\sqrt{3}∣a∣=3,∣b→∣=2\vert {\overrightarrow{b}}\vert =2∣b∣=2,且(a→+b→)⊥a→(\overrightarrow{a}+\overrightarrow{b})\bot \overrightarrow{a}(a+b)⊥a,则a→\overrightarrow{a}a与b→\overrightarrow{b}b的夹角是((( )))