25．已知向量∣a→∣=2,b→=(2,−5)\vert {\overrightarrow{a}}\vert =2,\overrightarrow{b}=({2,-\sqrt{5}})∣a∣=2,b=(2,−5)，若(a→+b→)⋅(2a→−b→)=−4({\overrightarrow{a}+\overrightarrow{b}})\cdot ({2\overrightarrow{a}-\overrightarrow{b}})=-4(a+b)⋅(2a−b)=−4，则a→\overrightarrow{a}a与b→\overrightarrow{b}b的夹角为 ___2π3\frac{2\pi }{3}32π___．